Advanced Organic Chemistry Practice Problems 2021 -

a) Draw the catalytic cycle for H/D or H/T exchange via Ir(III)-dihydride intermediates. b) Why does the reaction not label aromatic C–H bonds under these mild conditions? c) Propose a deuterium control experiment to confirm the mechanism.

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Reactions are allowed if the symmetry of the highest occupied molecular orbital ( a) Draw the catalytic cycle for H/D or